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61.
Here, an electrochemical sensor based on CeO2‐SnO2/Pd was prepared and used for highly selective and sensitive determination of nitrite in some real samples. This nanocomposite was characterized by various methods like X‐ray photoelectron spectroscopy, X‐ray diffraction, energy dispersive spectroscopy, Fourier‐transform infrared spectroscopy, field emission scanning electron microscopy, and transmission electron microscopy. The electrochemical behavior of the sensor was evaluated by cyclic voltammetry. The results showed excellent catalytic property of the nanocomposite as a an electrocatalyst for nitrite oxidation. In the following, the experimental parameters affecting the analytical signal for nitrite were optimized. Under the optimal conditions, the limit of detection and sensitivity of the sensor were calculated as 0.10 μM and 652.95 μA.mM?1.cm?2, respectively. Also, the response of the sensor was linear in the range of 0.36 to 2200 μM of nitrite. Finally, some of the inherent features of the sensor such as repeatability, reproducibility and stability were examined after evaluation of the sensor selectivity in the presence of several interfering species. 相似文献
62.
We have studied the spin polarized hot neutron matter in the presence of strong magnetic field. In this work, using the lowest order constrained variational method at finite temperature and employing AV18 nuclear potential, some thermodynamic properties of spin polarized neutron matter such as spin polarization parameter, free energy, equation of state and effective mass have been calculated. It has been shown that the strong magnetic field breaks the symmetry of the free energy, leading to a magnetized equilibrium state. We have found that the equation of state becomes stiffer by increasing both magnetic field and temperature. The magnetic field dependence of effective mass for the spin-up and spin-down neutrons has been investigated. 相似文献
63.
We study acoustic vortex in media with screw dislocation using the Katanaev–Volovich theory of defects. It is shown that the screw dislocation affects the beam?s orbital angular momentum and changes the acoustic vortex strength. This change is a manifestation of topological Dirac phase and is robust against fluctuations in the system. 相似文献
64.
We show that it is possible to use hard-Pomeron behavior to the gluon distribution and singlet structure function at low x. We derive a second-order independent differential equation for the gluon distribution and the singlet structure function.
In this approach, both singlet quarks and gluons have the same high-energy behavior at small x. These equations are derived from the next-to-leading order DGLAP evolution equations. All results can be consistently described
in the framework of perturbative QCD, which shows an increase of gluon distribution and singlet structure functions as x decreases. 相似文献
65.
We describe the catalytic activity of the first chimeric ligase containing a foldameric sequence of β- and γ-amino acids. The chimeric backbone provides for the spatial arrangement of all functional groups involved in the formation of the catalytic site to allow efficient catalysis to take place. Our finding indicates significant progress in the field of functionally active artificial motifs. 相似文献
66.
Mahdi Rezaei Sameti 《中国化学》2011,29(2):237-242
13C NMR chemical shifts have been calculated for structures of some substituted 3‐anilino‐2‐nitrobenzo‐[b]thiophenes ( 2 o) and 2‐anilino‐3‐nitrobenzo[b]thiophenes ( 3 o) derivatives containing OH, NH2, OMe, Me, Et, H, F, Cl and Br. The molecular structures were fully optimized using B3LYP/6‐31G(d,p). The calculation of the 13C shielding tensors employed the GAUSSIAN 03 implementation of the gauge‐including atomic orbital (GIAO) and continuous set of gauge transformations (CSGT) by using 6‐311++G(d,p) basis set at density functional levels of theories (DFT). The isotropic and the anisotropy parameters of chemical shielding for all compounds are calculated. The predicted 13C chemical shifts are derived from equation δ=δ0+δ where δ is the chemical shift, δ is the absolute shielding, and δ0 is the absolute shielding of the standard TMS. Excellent linear relationships have been observed between experimental and calculated 13C NMR chemical shifts for all derivatives 相似文献
67.
Rezaei M Norooz Oliaee J Moazzen-Ahmadi N McKellar AR 《Physical chemistry chemical physics : PCCP》2011,13(27):12635-12639
Infrared spectra of a carbon disulfide trimer formed in a pulsed supersonic slit-jet expansion are obtained via direct absorption of a tuneable diode laser in the region of the CS(2)ν(3) fundamental (~1535 cm(-1)). This is the first high-resolution spectroscopic observation of (CS(2))(3). Two bands sharing the same lower state are assigned to ((12)C(32)S(2))(3). These correspond to the two infrared active trimer vibrations (a parallel and a perpendicular band) of the constituent CS(2) monomer asymmetric stretches. The weaker perpendicular band is centered at 1524.613 cm(-1), shifted by -10.74 cm(-1) with respect to the free CS(2) monomer. The parallel band is centered at 1545.669 cm(-1), a vibrational shift of +10.31 cm(-1). Transitions with K≠ 3n and those with K = 0, J = odd in the ground state are absent, establishing that this trimer has D(3) symmetry. The two parameters required to define this structure are determined to be 3.811 ? for the C-C bond distance and 61.8° for the angle between a monomer axis and the plane containing the C atoms. In addition, a parallel band arising from trimers with a single (34)S substitution is observed around 1544.46 cm(-1). Together with the recently observed cross-shaped CS(2) dimer, these results indicate a tendency for CS(2) to form highly symmetric clusters. 相似文献
68.
M.J. KarimiG. Rezaei 《Physica B: Condensed Matter》2011,406(23):4423-4428
In this work, influences of external electric and magnetic fields on the optical rectification coefficient, the linear and the third-order nonlinear optical absorption coefficients as well as refractive index changes of finite semi-parabolic quantum dots are investigated. In this regard, energy eigenvalues and eigenfunctions of the system are calculated numerically, and optical properties are obtained using the compact density matrix approach. The results show that external electric and magnetic fields have a great influence on these optical quantities. 相似文献
69.
Some properties of pseudoinvex functions, defined by means of limiting subdifferential, are obtained. Furthermore, the equivalence between vector variational-like inequalities involving limiting subdifferential and vector optimization problems are studied under pseudoinvexity condition. 相似文献
70.
G.Rezaei Behbehani A.A.Saboury M.Mohebbian S.Tahmasbi Sarvestani M.Poorheravi 《中国化学快报》2009,20(11):1389-1392
Cyanide ion was studied as an inhibitor of Jack bean urease at 300 K in 30 mmol/L tris buffer,pH 7.The inhibition was investigated by isothermal titration calorimetry(ITC).The extended solvation model was used for CN~- + JBU interaction over the whole range of CN~- concentrations.The binding parameters recovered from the solvation model were attributed to the cyanide ion interaction.It was found that cyanide ion acted as a non-cooperative inhibitor of urease,and there is a set of 12±0.12 identical and in... 相似文献